Regenerable MgO-based sorbents for high-temperature CO2 removal from syngas: 1. Sorbent development, evaluation, and reaction modeling

Highly reactive and mechanically strong low-cost regenerable MgO-based sorbents were prepared by modification of dolomite which involved partial calcinations followed by impregnation with a potassium-based salt. The sorbents are capable of removing CO₂ from gasification-based processes such as Integrated Gasification Combined Cycle (IGCC). The sorbents have high reactivity and good capacity toward CO₂ absorption in the temperature range of 300-450 °C at 20 atm. and can be easily regenerated at 500 °C. The reaction appears to be first order with respect to CO₂ concentration with an activation energy of 44 kJ/mol. The reactivity and the absorption capacity of the sorbents increase with increasing temperature, as long as the partial pressure of CO₂ is above the equilibrium value for sorbent carbonation. The reactivity of the sorbents appears to improve in the presence of steam, which is likely due to the increase in the BET surface area and the porosity of the sorbent. A two-zone expanding grain model, consisting of a high-reactivity outer shell and a low-reactivity inner core is shown to provide an excellent fit to the TGA experimental data on sorbent carbonation at various operating conditions.     

Critical moisture content for microbial growth in dried food‐processing residues

BACKGROUND: Food‐processing residues are good feedstocks for biofuel and biochemical production because they have high energy content and are abundant. Year‐round biofuel and biochemical production requires proper storage to prevent microbial decomposition and thermal runaway. In this study, microbial activity of tomato pomace (TP), grape pomace (GP), fermented grape pomace (FGP) and sugar beet pulp (SBP) was monitored at nine different moisture contents. RESULTS: Maximum and cumulative respirations for each feedstock with respect to moisture content followed a sigmoidal relationship. The critical moisture content below which no microbial activity was detected for SBP, TP, FGP and GP was 24–31, 16–21, 23–33 and 43–46% (dry basis) respectively. A logarithmic relationship was observed (R² = 0.94) between critical moisture content and initial water‐soluble carbohydrate (WSC) content of the processing residues. CONCLUSION: The critical moisture content below which no microbial activity was detected and the relationship between critical moisture content and initial WSC content were determined in this study for four food‐processing residues. Both parameters permit evaluation of the potential for deterioration of food‐processing residues during storage based on moisture content and WSC content. Copyright © 2010 Society of Chemical Industry     

Study of polyamide 12 crystallization behavior within rotational molding process

Our study is focused on the investigation of polyamide 12 (PA 12) grade behavior in rotational molding process. Hence, some rotational molding tests of polyamide 12 were conducted on a STP LAB 40 machine. To simulate the cooling stage within the rotational molding, the crystallization behavior of polyamide 12 was studied using differential scanning calorimetry technique and the obtained results for non-isothermal crystallization were fitted with Ozawa model. Furthermore, morphology survey has been carried out by a hot stage method using a microscope to investigate the spherulites evolution which depends on the temperature. The micro-tensile properties have been studied using micro-tensile bench (MVTV2) to explain the mechanical behavior of polyamide 12 during crystallization. As a result, the rotational molding of PA 12 was successfully carried out. The simulation of the melting and crystallization stages, by application of Ozawa model coupled with enthalpy method gave a good representation of experimental data on one hand. On the other hand, all characterization revealed useful information to understand the different phenomena that govern the rotational molding process.     

N ‐acetylcysteine–PLGA nano‐conjugate: effects on cellular toxicity and uptake of gadopentate dimeglumine

Gadolinium as a contrast agent in MRI technique combined with DTPA causes contrast induced nephropathy (CIN) and nephrogenic systemic fibrosis (NSF) which can reduce by usage of antioxidants such as N‐acetyl cysteine by increasing the membrane''s permeability leads to lower cytotoxicity. In this study, N ‐acetyl cysteine‐PLGA Nano‐conjugate was synthesized according to stoichiometric rules of molar ratios andafter assessment by FTIR, NMR spectroscopy and Atomic Force Microscopy (AFM) imaging was combined with Magnevist® (gadopentetate dimeglumine) and its effects on the renal cells were evaluated. MTT [3‐(4,5‐Dimethylthiazol‐2‐yl)‐2,5‐Diphenyltetrazolium Bromide] and cellular uptake assays have indicated relatively significant toxicity of magnevist (P  < 0.05) on three cell lines including HEK293, MCF7 and L929 compared to other synthesized ligands that shown no toxicity. Moreover, systemic evaluation has shown no notable changes of blood urea nitrogen (BUN) and creatinine in kidney of mice. In consequence, antioxidant effect was increased as well as the renal toxicity of the contrast agent reduced at the cell level. As a result, PLGA‐NAC nano‐conjugate can be a promising choice for decreasing the magnevist toxicity for treatment and prevention of CIN and will be able to open a new horizon to research on reduction of toxicity of contrast agents by using nanoparticles.Inspec keywords: blood, toxicology, nanofabrication, cellular biophysics, biomedical materials, nanoparticles, chromatography, cancer, biodegradable materials, biomedical MRI, kidney, pH, nanomedicine, patient treatment, diseases, atomic force microscopy, Fourier transform infrared spectraOther keywords: cellular toxicity, gadopentate dimeglumine, contrast agent, magnetic resonance imaging technique, diethylenetriamine pentaacetate, contrast‐induced nephropathy, nephrogenic systemic fibrosis, stoichiometric rules, molar ratios, dimethyl sulphoxide solution, chromatography techniques, nuclear magnetic resonance spectroscopy, atomic force microscopy imaging, Magnevist®, gadopentetate dimeglumine, renal cells, MTT cytotoxicity, human embryonic kidney‐293, L929 cell lines, in vitro conditions, cellular uptake assays, Magnevist uptake, antioxidant effect, renal toxicity, cell level, PLGA nanocarrier, acetylcysteine nanoconjugate, Magnevist toxicity, N‐acetylcysteine–PLGA nano‐conjugate, N‐acetyl cysteine‐poly‐lactic‐co‐glycolic acid nanoconjugate     

Creating probabilistic databases from duplicated data

A major source of uncertainty in databases is the presence of duplicate items, i.e., records that refer to the same real-world entity. However, accurate deduplication is a difficult task and imperfect data cleaning may result in loss of valuable information. A reasonable alternative approach is to keep duplicates when the correct cleaning strategy is not certain, and utilize an efficient probabilistic query-answering technique to return query results along with probabilities of each answer being correct. In this paper, we present a flexible modular framework for scalably creating a probabilistic database out of a dirty relation of duplicated data and overview the challenges raised in utilizing this framework for large relations of string data. We study the problem of associating probabilities with duplicates that are detected using state-of-the-art scalable approximate join methods. We argue that standard thresholding techniques are not sufficiently robust for this task, and propose new clustering algorithms suitable for inferring duplicates and their associated probabilities. We show that the inferred probabilities accurately reflect the error in duplicate records.     

Modelling and parameter estimation of ultra-dispersed in situ catalytic upgrading experiments in a batch reactor

In situ catalytic upgrading of heavy oil and bitumen has been suggested and tested in the laboratory for utilization of heavy oil resources. Experimental observations have demonstrated potential, so this innovative recovery technique may have a role in the development of large resources of heavy oil and bitumen. Accurate analytical and numerical modelling is necessary in order to correctly interpret experimental measurements of the in situ upgrading, leading to a better understanding and design of field-scale processes. In this paper, we present modelling and parameter estimation for ultra-dispersed catalytic upgrading experiments conducted in a batch reactor. The Monte Carlo simulation technique was used to estimate the most appropriate reaction parameters. The combination of an analytical batch reactor model and the Monte Carlo simulation technique allows for the fast generation of a large number of upgrading experiment realizations. Comparisons of analytical modelling results with the experimental measurements of the upgrading experiments at different temperatures are in close agreement. Results reveal that ultra-dispersed catalytic upgrading in a batch reactor results in a fairly high residue conversion and can potentially increase the API gravity of the produced oil.     

Synthesis,characterization, thermal and optical properties of soluble polyimides derived from an unsymmetrical diamine

A new unsymmetrical diamine monomer, 2,4‐diaminophenyl [4′‐(2′′,6′′‐diphenyl‐4′′‐pyridyl)phenyl]ether, was successfully synthesized by nucleophilic substitution of 1‐chloro‐2,4‐dinitrobenzene with 4‐(2′,6′‐diphenyl‐4′‐pyridyl) phenol. The diamine monomer was characterized by FTIR, ¹H and ¹³C NMR, and elemental analysis techniques and used for the preparation of novel polyimides (PIs) by reaction with commercially available tetracarboxylic dianhydrides such as pyromellitic dianhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride, and bicyclo[2.2.2]‐oct‐7‐ene‐2,3,5,6‐tetracarboxylic dianhydride. These PIs with inherent viscosities ranged from 0.43 to 0.48 dL/g were readily soluble in many organic solvents and afforded tough and flexible films by solution casting. These polymers exhibited T_gs between 237 and 294°C, and 10% weight loss temperatures in excess of 500°C with up to 56% char yield at 600°C in air. Their maximum fluorescence emission in dilute (0.2 g/dL) NMP solution appeared at 450 nm. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Wind-tunnel investigation of icing of an inclined cylinder

The effects of varying the angle of wind velocity and axis of a cylindrical icing object around all of the three mutually perpendicular axes are studied experimentally. The mass, shape and profile of ice accretion obtained in a horizontal icing wind tunnel are investigated as functions of cylinder inclination. The icing object is exposed to two types of aerosol cloud, which are created by different procedures: (i) injecting small droplets horizontally into cold air flow, (ii) injecting vertically falling large droplets into cold air flow; so that the resulting conditions simulate in-cloud icing and freezing rain, respectively. Observations reveal the effects of varying each angle on the mass, shape and profile of ice accreted under both conditions.     

Dielectric spectroscopy techniques as quality control tool: a feasibility study - [feature article]

In this article, the feasibility of using time- and frequency-domain dielectric spectroscopy measurements to monitor the condition of oil-impregnated paper (OIP) condenser bushings is discussed.